Time to join the present. The 32 volt systems of the past will not give you a good return on any investment.
The LiFePo batteries are a century or more modern than the old lead acid batteries.
Charge efficiency in far better. Charge loss over time is next to nothing. Capacity is far better for both size and weight and the life expectancy is about 10x the number of cycles.
If you want add a second alternator on an engine to keep the bank charged when cruising without the generator running.
I switched to 12 volt, everything except for the Windlass, it is 24 volt, about 11 maybe 12 years ago, and there was some pushback here. I will never hump a 8D 8volt battery again. I recently replaced a shower sump, the entire sump for $40, that would be $100+ just for the pump in 32 volt.
12 or 24 volt is the way to go, I recommend 12 volt there are more 12 components than ever. Even something a common as a bilge pump is harder to find in 32 volt today.
My plan thus far ...
3000w Victron, 24v (or 48v?), Inverter/Charger
4 x 12v 200AH AGM Deep Cycle Batteries
Remote at helm next to my generator remote
I still need to look at how to wire this in. My breakers are on two legs. How can you supply power from a single 120v inverter to both legs? I don't mind turning off the high load stuff when on inverter, we do that anyways, prior to disconnecting shore power. So I don't need to rewire the breakers for that.
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I just bought a 32v Rule bilge pump. All of that stuff still seems to be available fine. Not really a comparison between adding something new, that doesn't have to be 32v versus replacing $1000's worth of existing stuff and wire that doesn't have to be replaced. I understand the urge, and if you have the $$$, no problem.
Theres all kinds of options. 12 and 24 volt being the most common.
As for batteries look at the comparison of 2 x 160 AH LiFePo giving about 240 usable compared to 4 x 100 AH AGM batteries yielding 200 usable AH.
LiFePo will give 10x the cycle life and charge much faster. Also will not require to be fully recharged without loosing life expectancy.
A customers wife did the mathematics a while back and said go with the LiFePo because the cost of the AGM at the first change out was almost a wash.